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Chemical Reactions

Chemical Reactions. Determining Products of Reactions AP Chemistry 2012-2013. Types of Reactions. Metathesis – no transfer of electrons Double Replacement Precipitation Reactions Solids Gases Acid-Base Reactions. Types of Reactions Continued.

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Chemical Reactions

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  1. Chemical Reactions Determining Products of Reactions AP Chemistry 2012-2013

  2. Types of Reactions • Metathesis – no transfer of electrons • Double Replacement • Precipitation Reactions • Solids • Gases • Acid-Base Reactions

  3. Types of Reactions Continued • Oxidation-Reduction Reactions – transfer of electrons • Some types of redox reactions include • Single Replacement • Combustion • Synthesis • Decomposition

  4. Writing the equations • NET IONIC ONLY • Balanced for mass and charge • Examples

  5. Two Elements as Reactants • Two elements as reactants • Synthesis • Be sure to assign the most common oxidation states to the elements • Examples • Solid zinc is heated in chlorine gas. • Solid sulfur is burned in oxygen

  6. Example Reactions • Answers • Zn + Cl2 ZnCl2 • S + O2  SO2

  7. Single Reactant • Must be a Decomposition • When unsure, break the compound into its elements • Most do not completely decompose but produce • Ionic salts and • oxide gases • Example • Solid calcium carbonate is heated • A piece of solid potassium nitrate is heated

  8. Example Reactions • Answers • CaCO3 CaO + CO2 • 2 KNO3  2 KNO2 + O2

  9. Water is a Reactant • Three variations • Pure metal or metal hydride in water makes a base and hydrogen gas. • Sodium metal is added to distilled water • Lithium hydride is added to distilled water • A metal oxide in water will produce a base. • Solid barium oxide is added to water. • A nonmetal oxide in water will produce an acid. • Solid dinitrogenpentoxide is added to water. • Carbon dioxide gas is bubbled through water.

  10. Examples • Answers • Na + 2 H2O  Na+ + 2 OH- + H2 • LiH + 2 H2O  Li+ + 2 OH- + H2 • BaO + H2O  Ba2+ + 2 OH- • N2O5 + H2O  2 H+ + 2 NO3- • CO2 + H2O  H2CO3

  11. Mixture of two salt solutions • Precipitation Reactions – KNOW YOUR SOLUBILITY RULES AND COMMON IONS • Net ionic and balanced • Examples • A solution of silver nitrate is added to a solution of potassium iodide • Solutions of lead(II) nitrate and tri-potassium phosphate are mixed

  12. Examples • Ag+ + I-  AgI • 3 Pb2+ + 2 PO43-  Pb3(PO4)2

  13. Combustion of carbon compounds • Combustion is the reaction with oxygen • Produces carbon dioxide and water when enough oxygen is present • Examples • Propane is burned in air. • Carbon disulfide is burned in excess oxygen.

  14. Examples • C3H8 + 5 O2 3 CO2 + 4 H2O • CS2 + 3 O2  CO2 + 2 SO2

  15. Single replacement • Transition metal placed in a solution • Oxidation-reduction reaction • Metal will always be oxidized M+x • Neutral conditions • Ion in solution will be reduced • Examples • Solid manganese flakes are placed in a solution of copper (II) sulfate • Iron filings are placed in a solution of iron (III) sulfate.

  16. Examples • Mn + Cu2+  Mn2+ + Cu • Fe + 2 Fe3+ 3 Fe 2+ • Fe  Fe 2+ + 2e- • Fe 3+ + 1 e-  Fe 2+

  17. Single replacement (2) • Acidic conditions with an oxoacid • Anion of the oxoacid will be reduced to an oxide gas and water will form • Examples • Copper is immersed in dilute nitric acid • Lead is immersed in concentrated warm sulfuric acid

  18. Examples • Cu + H+ + NO3- Cu2+ + NO + H2O • Pb + H+ + HSO4-2  Pb2+ + SO2 + H2O

  19. Formation of complex ions • Look for transition metal ions in solution with NH3, OH-, CN-, or SCN- • Don’t worry about how many you put on the metal ion • Usually combine in 1, 2, 4, or 6 • Add the charges together to determine the charge on the whole ion • Example • Excess ammonia is added to a solution of silver nitrate • Ag+ + NH3 Ag(NH3)2+

  20. More examples of complex ions • A solution of sodium cyanide is added to a solution of iron(II) chloride • Fe 2+ + CN- Fe(CN)64- • Charges are determined by adding all the ions in the complex • 2+ + 6 x -1 = -4

  21. Videos of reactions – alkali metals and water • http://www.youtube.com/watch?v=oqMN3y8k9So • http://www.youtube.com/watch?v=Jy1DC6Euqj4 • http://www.youtube.com/watch?v=92Mfric7JUc

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