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Verkleg eðlisefnafræði ÚF/SÝN litrófsgreining;

Verkleg eðlisefnafræði ÚF/SÝN litrófsgreining; Jafnvægisfasti ákvarðaður með litrófsgreiningu dæmi: Tyrosine Sbr verkleg æf. B4a: http://notendur.hi.is/agust/kennsla/ee11/eeabv11/verkl/eeabv-b4a.pdf Sjá verkefni (tyrosine):

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Verkleg eðlisefnafræði ÚF/SÝN litrófsgreining;

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  1. Verkleg eðlisefnafræði ÚF/SÝN litrófsgreining; Jafnvægisfasti ákvarðaður með litrófsgreiningudæmi: Tyrosine Sbr verkleg æf. B4a:http://notendur.hi.is/agust/kennsla/ee11/eeabv11/verkl/eeabv-b4a.pdf Sjá verkefni (tyrosine): http://notendur.hi.is/agust/kennsla/ee11/eeabv11/verkefni/eeabv-b4a.doc

  2. Ákvarða Gleypnistuðla (e) sýru og basa forma tyrosine við 270 nm og 287 nm: ATH: a =L*e, L = 1 cm => a = e Abs./Gl. Skv. “IGOR”: Coefficient values ± one standard deviation a =0.01 ± 2.64e-015 hallatala:b =1440 ± 3.4e-012 270 nm = a270,BH Súrar lausnir Coefficient values ± one standard deviation a =6.0137e-017 ± 6.01e-017 hallatala:b =40 ± 7.73e-014 = a287,BH 287 nm Styrkur/M Abs./Gl. Coefficient values ± one standard deviation a =-0.038333 ± 0.00898 b =2620 ± 11.5 287 nm = a287,B- Basískar lausnir Coefficient values ± one standard deviation a =0.0016667 ± 0.00898 b =1020 ± 11.5 270 nm = a270,B- Styrkur/M

  3. Leysi saman jöfnur: A270 = a270,BH[BH] + a270,B-[B-]                  (3a) A287 = a287,BH[BH] + a287,B-[B-]                  (3b) Þá fæst: Sbr.:http://notendur.hi.is/agust/kennsla/ee11/eeabv11/verkl/eeabv-b4a.pdf =meðaltal Sjá útreikninga: http://notendur.hi.is/agust/kennsla/ee11/eeabv11/verkefni/eeabv-b4a.xls Ágúst Kvaran, updated 09.11.11

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