Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 2007
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AMGI/EURASAP Workshop Air Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007. Andrija Mohorovičić Geophysical Institute Department of Geophysics , Faculty of Science University of Zagreb, Croatia. Zvjezdana Bencetić Klaić [email protected]

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Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 2007

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

Zvjezdana Bencetić [email protected]

The European Association for the Science of Air Pollution

MAJOR AIR QUALITY CONCERNS IN CROATIA

  • Pollutants?

  • Sources?

  • Incidents!


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 20071

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Main pollutants

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/ )

SOx (SO2 and SO3)

NOx (NO2 and NO)

Gaseous:

NH3

NMVOC

CO


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 20072

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Main pollutants

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/ )

TSP

Particulates:

(PM10)

(PM2.5)


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 20073

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Main pollutants

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/ )

Arsenic (As)

Cadmium (Cd)

Chromium (Cr)

Copper (Cu)

Mercury (Hg)

Nickel (Ni)

Lead (Pb)

Selenium (Se)

Zinc (Zn)

Heavy metals:


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 20074

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Main pollutants

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/ )

Lindane (HCH)

Pentachlorophenol (PCP)

Hexachlorobenzene (HCB)

Dioxins and Furans (DIOX)

Polycyclic aromatic hydrocarbons (PAHs)

Persistent organic pollutants:


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 20075

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Main pollutants

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/ )

Short Chained Chlorinated Paraffins (SCCP)

Polychlorinated biphenyls (PCBs)

Aldrin

Chlordane

Chlordecone

Persistent organic pollutants:


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 20076

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Main pollutants

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/ )

Dichlorodiphenyl-trichloroethane (DDT)

Dieldrin

Heptachlor

Hexabromobiphenyl

Mirex

Toxaphene

Persistent organic pollutants:


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 20077

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Croatian anthropogenic emissions, gaseous (2002)

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

(103 kg/year)


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 20078

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Intercomparison (2000)

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/ )

Austria

Croatia (2000)

Germany

Croatia (1990)

Germany

France

Slovakia

Croatia (2000)

Bulgaria

Italy

EU

Austria

Poland

UK

Czech Republic

EU

Slovakia

Italy

Croatia (1990)

France

UK

Poland

Slovenia

Slovenia

USA

Czech Republic

Bulgaria

USA

kg SO2 / inhabitant

kg NOx / inhabitant


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 20079

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Croatian anthropogenic emissions, gaseous (2002)

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

(103 kg/year)


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200710

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Croatian anthropogenic emissions, particulates (2002)

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

(103 kg/year)


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200711

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Croatian anthropogenic emissions, heavy metals (2002)

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

(kg/year)


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200712

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Croatian anthropogenic emissions, heavy metals (2002)

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

(kg/year)


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200713

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Croatian anthropogenic emissions, persistent organic pollutants (2002)

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

(kg/year)


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200714

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Sources of acidifying gases

(SO2, NOx,

NH3) (2002)

Burning -energy production

16 %

Burning –

non-industrial 4 %

Agriculture

42 %

Burning –

industrial

13 %

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

Road

traffic

12 %

Production processes 6 %

Other mobile

sources and machines 7 %


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200715

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Other mobile

sources and machines 4 %

Road

traffic

8 %

SO2

(2002)

Production processes

9 %

Burning -energy production

35 %

Burning –

industrial

34 %

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

Burning –

non-industrial 10 %


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200716

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

NOx

(2002)

Other mobile

sources and machines

23 %

Burning - energy production

19 %

Burning –

non-industrial

5 %

Burning –industrial

10 %

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

Production processes

2 %

Road traffic

41 %


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200717

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Other

sources 1 %

Other mobile sources and machines 9 %

CO

(2002)

Burning –

non-industrial

32 %

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

Road traffic

49 %

Burning –industrial 9 %

Production processes 1 %


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200718

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Production processes

5 %

NH3

(2002)

Road traffic

1 %

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

Agriculture

94 %


Andrija mohorovi i geophysical institute department of geophysics faculty of science

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Particles

(2002)

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

PM10

TSP

PM2.5


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200719

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Burning –industrial 1 %

Pb

(2002)

Burning - energy production

1 %

Production processes

4 %

Other sources 1 %

Road traffic

93 %

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)


Andrija mohorovi i geophysical institute department of geophysics faculty of science

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Fossil fuel and geothermal energy distribution

1 %

Waste treatment and deposition 2 %

Hg

(2002)

Production processes

3 %

Burning –

energy

production

36 %

Burning –industrial 30 %

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

Burning –

non-industrial 28 %


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200720

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Other heavy metals

(2002)

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200721

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Persistent organic pollutants

(2002)

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200722

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Main individual SO2 sources

(2002)

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200723

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Main individual NOx sources

(2002)

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200724

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Main individual CO sources

(2002)

(source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200725

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Some hot spots

2

1. Rijeka

20% of Croatian

SO2 (2002) from

oil refinery and TE

4

1

3

5

2. Zagreb

4% of Croatian NOx (2002) from

TE-TO and EL-TO

3. Sisak

15% of CroatianSO2 (2002) from

oil refinery and TE

4. Kutina

9% of CroatianSO2 (2002) from Petrokemija

5. Plomin

6% of CroatianSO2

and 5% NO2 (2002)

from TE


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200726

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Current state network

2

4

1

3

5

http://zrak.mzopu.hr/glavni.asp


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200727

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Recent serious incidents - 1

2

4

1

3

6

Karlovac, 23 February 2007

5

Beer factory –unlawful CO2 emission  1 died


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200728

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Recent serious incidents - 2

2

4

1

3

Sisak, January 2007

5

Oil refinery– H2S pollution


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200729

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Recent serious incidents - 2

H2S (µg m-3) – daily

6. Sisak, January 2007

C6H6 (µg m-3) – daily

Oil refinery– H2S pollution

1, 13 and 16 January

PM10 (µg m-3) – daily

http://zrak.mzopu.hr/


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200730

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Recent serious incidents - 2

CO (µg m-3) – hourly

H2S (µg m-3) – hourly

Sisak, 1 January 2007

C6H6 (µg m-3) – hourly

PM10 (µg m-3) – hourly

http://zrak.mzopu.hr/


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200731

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Recent serious incidents - 2

CO (µg m-3) – hourly values

H2S (µg m-3) – hourly values

Sisak

13 – 16 January 2007

C6H6 (µg m-3) – hourly values

PM10 (µg m-3) – daily values

http://zrak.mzopu.hr/


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200732

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Recent serious incidents – 3

NO2

Sisak

20 February 2007; 15:15

Crude oil spill  100 m high jet

CO

H2S

SO2

C6H6

PM10


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200733

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

More about Sisak

1 - 12 April 2007

H2S (µg m-3) – daily

PM10 (µg m-3) – daily

SO2 (µg m-3) – daily


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200734

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Recent serious incidents – 4

2

4

1

3

Rijeka, 3 - 5 February 2002

5

Jeričević et al., 2004

On 4 February a warning was sent out to the public not to expose outdoors!


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200735

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Other sites

Kutina, PM10

Rijeka2, O3

Zagreb1, NO2

Zagreb1, PM10

Zagreb3, O3

Osijek, PM10


Amgi eurasap workshop air quality management monitoring modeling and effects zagreb may 24 26 200736

AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007

Andrija Mohorovičić Geophysical Institute

Department of Geophysics, Faculty of Science

University of Zagreb, Croatia

The European Association for the Science of Air Pollution

Conclusion

  • Old technologies

  • Unlawful emissions

  • Answers?


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