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10.4 配合物的应用

10.4 配合物的应用. 10.4 配合物的应用. ● 鉴别离子 [Fe(CN) 6 ] 4- + Fe 3+ [Fe( Ⅱ ) (CN) 6 Fe (Ⅲ) ] - + CN - （兰） [Fe(CN) 6 ] 3- + Fe 2+ [Fe( Ⅱ ) (CN) 6 Fe (Ⅲ)] - + CN - （兰） Ni 2+ + EDTA 　 红色 ●温法冶炼 例如用 CN - 溶解重金属 ●金属的分离与提纯

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10.4 配合物的应用

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  1. 10.4 配合物的应用 10.4 配合物的应用 ●鉴别离子 [Fe(CN)6]4- + Fe3+ [Fe(Ⅱ) (CN)6 Fe (Ⅲ) ]- + CN -（兰） [Fe(CN)6]3- + Fe2+ [Fe(Ⅱ) (CN)6 Fe (Ⅲ)]- + CN -（兰） Ni2+ + EDTA 　 红色 ●温法冶炼 例如用CN-溶解重金属 ●金属的分离与提纯 不纯的金属，生成M(CO)x M + xCO ●在催化剂使用中的应用 CH2=CH2 + 1/2O2 +(PdCl2) CH3CHO

  2. 10.4 配合物的应用 ●电镀工业中的应用 ●污水处理 CN- + ClO- + OH- CNO- + Cl- + H2O CN- + Fe3+ [Fe(CN)6]3- ●生物体中的配位化学 Fe2+ + 卟啉 铁卟啉（血红素） Mg2+ + 卟啉 镁卟啉（叶绿素） Co3+ + 卟啉 钴卟啉配合物（B12）等

  3. 再见

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