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The Future (?)

The Future (?). Data from past 100 years: CO 2 conc. has risen by 25% average temp. increase: 0.5-0.7 0 C. Current: doubling the CO 2 conc.  + 1.8-6.3 0 C (2.5-10.4 0 F by 2100) CO 2 is a major part of the greenhouse effect Earth’s average temperature is increasing.

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The Future (?)

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  1. The Future (?) Data from past 100 years: CO2 conc. has risen by 25% average temp. increase: 0.5-0.7 0C Current: doubling the CO2 conc.  +1.8-6.3 0C (2.5-10.4 0F by 2100) CO2 is a major part of the greenhouse effect Earth’s average temperature is increasing

  2. Shape of Molecules (3.3) Greenhouse gases: CO2, CH4, N2O, O3, H2O, CFCs Not greenhouse gases: O2, N2, Ar Why the difference? Shape!

  3. VSEPR Lewis structures: 2D Reality: 3D • Bonds are made of electrons • Negatively charged • Repel each other (still attracted to protons) • Want to be as far apart as possible!

  4. H H . 109 5 C H H C H H H H Example: Methane CH4: tetrahedral

  5. Fig.3.7

  6. Fig.3.8

  7. Fig.3.9 “Trigonal Pyrimidal”

  8. Fig.3.10 “Bent”

  9. Fig.3.11 “Linear”

  10. Fig.03.12 “Bent”

  11. Light and Molecules (3.4) UVB, UVC: Bonds break IR: Can’t break (not enough energy) Can cause vibrations Shape  HOW a molecule can vibrate Which wavelength? Bond strength & flexibility, atom masses

  12. Fig.03.13

  13. Fig.3.14

  14. What about O2 and N2? • Do not absorb IR radiation • IR does not cause vibration • Can’t “trap” heat • Not greenhouse gases

  15. Fig.3.16

  16. The Carbon Cycle Sect. 3.5

  17. Fig. 3.17 Where does CO2 come from? Where does it go?

  18. water CaCO3 (limestone) Volcanic vents Respiration/decay Plants & animals Sources of CO2 (natural) CO2

  19. Respiration water Plants H2CO3 Mineral Dep. Pressure/time Fossil Fuels Consumption of CO2 CO2

  20. Fossil Fuel Contribution to Atmospheric CO2: • 6-7 billion tons of carbon released • ~ ½ goes to atmosphere • Since 1860: • CO2 conc. 290 ppm  375 ppm, • Increases ~1.5 ppm/year.

  21. Deforestation • Adds CO2 to air (burning/decay) • Takes away a CO2 remover (trees/plants)

  22. Excess CO2 global warming • Increase in atmos. CO2 is a concern • 3.1-3.5 Gt of carbon/year • How much CO2 is added per year?

  23. Mass # Quantitative Concepts: Mass (3.6) How much does an atom weigh? Depends on the atom Standard: Carbon-12 Atomic #: 6 6p, 6n One Carbon 12 = 12 amu

  24. Atomic # Atomic Mass C 6 Symbol Carbon Name 12.01

  25. What’s with the 12.01??? Carbon: 3 isotopes Carbon-12: 98.89% Carbon-13: 1.11% Carbon-14: ~0.00% Average atomic mass for C = 12.01 amu Atomic mass is an average of all carbon atoms

  26. NO carbon atoms weigh 12.01 amu • Treat ALL carbon atoms as though they weigh 12.01 • 1 Tbs of carbon has about 6.022 x 1023 carbon atoms • 602,200,000,000,000,000,000,000 • Dealing with large numbers of atoms • Average is best

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