1 / 25

Margarita Loredo -Cancino

Synthesis and characterization of zinc and cupper MOFs derived from diazo and oxim ligands for wastewater treatment. Margarita Loredo -Cancino R. Chan-Navarro | N.E. Dávila-Guzmán | D.A. De Haro -Del Río | M. Vázquez- Mozencahuatzi |. ADSORPTION. Zheng et al. 2012. Li et al. 2015.

dori
Download Presentation

Margarita Loredo -Cancino

An Image/Link below is provided (as is) to download presentation Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author. Content is provided to you AS IS for your information and personal use only. Download presentation by click this link. While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server. During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

Presentation Transcript

  1. Synthesis and characterization of zinc and cupper MOFs derived from diazo and oxim ligands for wastewater treatment Margarita Loredo-Cancino R. Chan-Navarro | N.E. Dávila-Guzmán | D.A. De Haro-Del Río | M. Vázquez-Mozencahuatzi |

  2. ADSORPTION Zheng et al. 2012 Liet al. 2015

  3. Adsorbentcharacteristics

  4. Adsorbents

  5. MOF • Metal ion and anorganicmolecule • 3D structures • High surfacearea (1500-7000 m2/g) • SeveralanalogousMOFs • Easytunability Xu et al. 2014, Rouquerolet al. 2014

  6. MOF

  7. Summary of MOFs as colorantadsorbent

  8. Objective

  9. Linker 1 5-formyl-8-hydroxyquinoline (precursor) 8-Hydroxyquinoline acid 4-amino benzoic linker 1

  10. Linker 2 4-formyl pyridine acid 4-amino benzoic

  11. Synthesis of coordinationpolymers

  12. Linker 1 4-amino acid benzoic P.F.=187-189 °C 5-formyl-8- hidroxyquinoline Linker 1 Yield = 92% Melting point = 300°C Color = yellow

  13. 2 3 4 9 10 5 11 14 15 8 H-(14, 16) 13 18 H-(11) H-(15,17) 19 7 6 1H PROTON NMR SPECTRA OF LINKER 1 1H (11) ~9.00ppm 1H (19) = 10.1 ppm 16 17 H-(2) H-(4) (García-López et al., 2014) H-(7) H-(3) H-(6) H-(19)

  14. 2 3 4 9 10 11 8 14 15 C17H12N2O3 13C (11) ~ 167 ppm 5 18 13 19 7 6 C15,C17 C14,C16 (García-López et al., 2014) 17 16 13C PROTON NMR SPECTRA OF LINKER 1 C5 C7 C6 C2 C4 C8 C18 C11 C19 C10 C3 C9 C13

  15. CHARACTERIZATION OF LINKER 2 Linker 2 Yield = 83% Melting point = 260 °C Color = white 5 4 3 7 10 11 6 14 9 15 2 1H and 13C PROTON NMR SPECTRA OF LINKER 2 13 12

  16. COORDINATION POLYMER 1 Ligante 1 PC 1 Yield = 83% Melting point  300 °C Color = Yellow

  17. Coordination polymer 2 Ligante 2 PC 2 Yield = 85% Melting point > 300 °C Color= white

  18. FT-IR SPECTRA OF LINKER 1 AND PC 1 (Reiss et al., 2015) (Mohammadikish, 2017) 3378 1608 υ (O-H)=3500-3000 cm-1 1638 1571 1697 υ (H2O)=3378 cm-1

  19. FT-IR SPECTRA OF LINKER 2 AND PC 2 (Reiss et al., 2015) (Mohammadikish, 2017) 3371 1608 υ (O-H)=3500-3000 cm-1 1645 1556 υ (H2O)=3371 cm-1 1697

  20. SUMMARY • Linkersweresuccessfullysyntethizedwithyieldabove 80%. • Precursor formationwasverifiedvia NMR 1H y 13C. • Zinc-linkercoordinationwasachieved and verifiedwiththedisplacement of C=O y C=N bands, as reported in literature.

  21. References Adhikari, Bimalendu, Goutam Palui, and Arindam Banerjee. 2009. “Self-AssemblingTripeptideBasedHydrogels and Their Use in Removal of DyesfromWaste-Water †.” 5(Scheme 1): 3452–60. Chang, L., Li, J., Duan, X., & Liu, W. (2015). Porouscarbonderivedfrom Metal-organicframework (MOF) forcapacitivedeionizationelectrode. Electrochimica Acta, 176, 956–964. http://doi.org/10.1016/j.electacta.2015.07.130 García-López, M. C., Muñoz-Flores, B. M., Jiménez-Pérez, V. M., Moggio, I., Arias, E., Chan-Navarro, R., & Santillan, R. (2014). Synthesis and photophysicalcharacterization of organotincompoundsderivedfromSchiff bases. Dyes and Pigments, 106(August), 188–196. http://doi.org/10.1016/j.dyepig.2014.02.021 Haque, E., Jun, J. W., & Jhung, S. H. (2011). Adsorptiveremoval of methylorange and methylenebluefromaqueoussolutionwith a metal organicframework material, ironterephthalate (MOF-235). Journal of HazardousMaterials, 185(1), 507–511. http://doi.org/10.1016/j.jhazmat.2010.09.035 Haque, E., Lee, J. E., Jang, I. T., Hwang, Y. K., Chang, J.-S., Jegal, J., & Jhung, S. H. (2010). Adsorptiveremoval of methylorangefromaqueoussolutionwith metal-organicframeworks, porouschromium-benzenedicarboxylates. Journal of HazardousMaterials, 181(1), 535–542. article. He, Qinqin, QiChen, MengmengLü, and XuetingLiu. 2014. “ChineseJournal of ChemicalEngineeringAdsorptionBehavior of Rhodamine B on UiO-66.” CJCHE 22(11–12): 1285–90. http://dx.doi.org/10.1016/j.cjche.2014.09.009. Hong-gui, D., Shuang-ling, J. I. N., Liang, Z., Yan-li, W., Bao-hua, L. U., Wen-ming, Q., & Li-cheng, L. (2012). Synthesis of porouscarbonsderivedfrom metal-organiccoordinationpolymers and theiradsorption performance forcarbondioxide. New CarbonMaterials, 27(3), 194–199. http://doi.org/10.1016/S1872-5805(12)60013-4. Inagaki, M., Toyoda, M., Soneda, Y., Tsujimura, S., & Morishita, T. (2016). Templatedmesoporouscarbons: Synthesis and applications. Carbon. http://doi.org/10.1016/j.carbon.2016.06.003

  22. Jiang, X. H., Wang, B. D., Yang, Z. Y., Liu, Y. C., Li, T. R., & Liu, Z. C. (2011). 8-Hydroxyquinoline-5-carbaldehyde Schiff-base as a highlyselective and sensitive Al 3+ sensor in weakacidaqueousmedium. InorganicChemistryCommunications, 14(8), 1224-1227. Leng, Chi-cheng, and Neville G Pinto. 1996. “AnInvestigation of theMechanisms of ChemicalRegeneration of ActivatedCarbon.” 5885(1994): 2024–31 Li, Xianghui et al. 2016. “AppliedSurfaceScience Fe-Based MOFs forEfficientAdsorption and Degradation of Acid Orange 7 in AqueousSolutionviaPersulfateActivation.” AppliedSurfaceScience 369: 130–36. http://dx.doi.org/10.1016/j.apsusc.2016.02.037. Li, Yu, KangZhou, Ming He, and JianfengYao. 2016. “Microporous and MesoporousMaterialsSynthesis of ZIF-8 and ZIF-67 UsingMixed-Base and TheirDyeAdsorption.” 234: 287–92. Lin, S., Song, Z., Che, G., Ren, A., Li, P., Liu, C., & Zhang, J. (2014). Adsorptionbehavior of metal-organicframeworksformethylenebluefromaqueoussolution. Microporous and MesoporousMaterials, 193, 27–34. http://doi.org/10.1016/j.micromeso.2014.03.004. Liu, B., Shioyama, H., Akita, T., & Xu, Q. (2008). Metal-organicframework as a templateforporouscarbonsynthesis. Journal of the American ChemicalSociety, 130(16), 5390–5391. Liu, Haochi, XiaohuiRen, and LigangChen. 2016. “Journal of Industrial and EngineeringChemistrySynthesis and Characterization of Magnetic Metal – Organic Framework fortheAdsorptiveRemoval of Rhodamine B fromAqueousSolution.” Journal of Industrial and EngineeringChemistry 34: 278–85. http://dx.doi.org/10.1016/j.jiec.2015.11.020. Mohammadikish, M. (2017). Facilesynthesis of novel zinc-based in fi nitecoordinationpolymernanoparticles. InorganicChemistryCommunications, 78, 48–51. http://doi.org/10.1016/j.inoche.2017.02.013

  23. Moradi, S. E., Dadfarnia, S., Shabani, A. M. H., Emami, S., Dadfarnia, S., Shabani, A. M. H., & Removal, S. E. (2015). Removal of congo red fromaqueoussolutionbyitssorptionontothe metal organicframework MIL-100 ( Fe ): equilibrium , kinetic and thermodynamicstudies. Desalination and WaterTreatment, 56(3), 710–722. http://doi.org/10.1080/19443994.2014.947328 Pandiaraj, Sekar, HarshithaBarikeAiyappa, Rahul Banerjee, and SreekumarKurungot. 2014. “Post Modification of MOF DerivedCarbonviagC 3 N 4 EntrapmentforanEfficient Metal-Free OxygenReductionReaction.” ChemicalCommunications 50(25): 3363–66. Reiss, A., Samide, A., Ciobanu, G., & Dabuleanu, I. (2015). Synthesis, spectralcharacterization and thermalbehaviour of new metal (ii) complexeswithschiff base derivedfromamoxicillin. Journal of theChileanChemicalSociety, 60(3), 3074–3079. Rouquerol, J., Rouquerol, F., Llewellyn, P., Maurin, G., & Sing, K. S. W. (2014). AdsorptionbyPowders and PorousSolids. AcademicPress. Wei, C., Li, X., Xu, F., Tan, H., Li, Z., Sun, L., & Song, Y. (2014). Metal organicframework-derivedanthill-likeCu@carbonnanocompositesfornonenzymaticglucose sensor. Anal. Methods, 6(5), 1550–1557. http://doi.org/10.1039/c3ay41764f Xu, H., Zhou, S., Xiao, L., Wang, H., Li, S., & Yuan, Q. (2015). Fabrication of a nitrogen-dopedgraphene quantum dotfrom MOF-derivedporouscarbon and itsapplicationforhighlyselectivefluorescencedetection of Fe 3+. Journal of MaterialsChemistry C, 3(2), 291–297. Yang, Cao, ShichuanWu, JianhuaCheng, and YuancaiChen. 2016. “Indium-Based Metal-Organic Framework / Graphite Oxide Composite as anEf Fi CientAdsorbent in theAdsorption of Rhodamine B fromAqueousSolution.” Journal of Alloys and Compounds 687: 804–12. http://dx.doi.org/10.1016/j.jallcom.2016.06.173. Yuan, Dingsheng et al. 2009. “Worm-likeMesoporousCarbonSynthesizedfrom Metal--OrganicCoordinationPolymersforSupercapacitors.” ElectrochemistryCommunications 11(6): 1191–94. Zou, Feng et al. 2014. “MOF-DerivedPorousZnO/ZnFe2O4/C OctahedrawithHollowInteriorsforHigh-RateLithium-Ion Batteries.” AdvancedMaterials 26(38): 6622–28.

  24. ¡THANKS FOR YOUR ATENTION!

  25. Purificación del precursor Extracción Soxlet Revelado cromatografía de capa fina Cromatografía de columna

More Related