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Reaktionsmechanismen der Ozongenerierung in der unteren Troposphäre

Reaktionsmechanismen der Ozongenerierung in der unteren Troposphäre. R – CH 3 + ·OH  R - ·CH 2 + H 2 O R – ·CH 2 + O 2  R – CH 2 O 2 · R – CH 2 O 2 · + NO  R – CH 2 O · + NO 2 R – CH 2 O· + O 2  R – CHO + HO 2 · NO + HO 2 ·  NO 2 + ·OH 2 NO 2  2 NO + 2 O

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Reaktionsmechanismen der Ozongenerierung in der unteren Troposphäre

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  1. Reaktionsmechanismen der Ozongenerierung in der unteren Troposphäre R – CH3 + ·OH  R - ·CH2 + H2O R – ·CH2 + O2  R – CH2O2· R – CH2O2· + NO  R – CH2O· + NO2 R – CH2O· + O2  R – CHO + HO2· NO + HO2· NO2 + ·OH 2 NO2 2 NO + 2 O 2 O + 2 O2  2 O3   Gesamtgleichung: R – CH3 + 4 O2 R – CHO + 2 O3 + H2O

  2. Entstehung ohne Kohlenwasserstoffe Photolyse bei UV-Einwirkung: λ = 400 nm 2 NO2 + 2 O2 2 NO + 2 O3 2 NO + O2  2 NO2 Bildung aus Schwefeldioxid SO2 + O2 + NO  SO3 + NO2 NO2 + O2  NO + O3

  3. Von Magnus Beyer Gesamtschule Mönchengladbach-Hardt magnus_beyer.jufo@web.de

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