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Practical aspects of structural tests of titanium-steel bonds made by explosive cladding and exposed to process thermal loads. Robert BAŃSKI Politechnika Opolska. xplomet. Maria SOZAŃSKA Politechnika Śląska. Zygmunt SZULC, Aleksander GAŁKA. Zakład Technologii

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  1. Practical aspects of structural tests of titanium-steel bonds made by explosive cladding and exposed to process thermal loads Robert BAŃSKI Politechnika Opolska xplomet Maria SOZAŃSKA Politechnika Śląska Zygmunt SZULC, Aleksander GAŁKA Zakład Technologii Wysokoenergetycznych „EXPLOMET” Gałka, Szulc, Sp.j. - 1 -

  2. Subjectaboutwhich we will not talking • About cladding elements to process apparatus • About cladding for electrotechnic, electrometallurgy and electrochemistry • About cladding bars, tubes and others… elementów.. - 2 -

  3. Subjectaboutwhich we will not talking • About conductive rails for electrolysers of chlorine • About Electrical Transition Joints (ETJ) STJ – Structural Transition Joints ETJ – Electric Transition Joints • About Structural Transition Joints (STJ) - 3 -

  4. Reactor Tubesheet First we have to make cladding plate : ASME SA-240 304 L + ASME SB 265 Gr.1, and later …. there is a question, is this should be heat treated or not? THIS WHAT WILL BE TALKING ABOUT ?

  5. CONTROL OF SET AND PROCESS Making cladding of Ti Gr.1 + 304 L (6 + 95 mm) Control of explosive’s thickness Measurement of detonation speed in productive set - 5 -

  6. And we back to the question, if cladding plate Ti Gr.1 + 304L should be heat treated or not? From cladding plate in sizes: (6+95) x 3150 x 3150 mm was taken test plate and test samples.

  7. Paramet ers of Heat Results of me ch anical test Treatment Number Rs – shear test Ro – tensile test of test plate T emp. Time [MPa] / średnia [MPa] / średnia ° [h] [ C ] W ith out W ith out Wi th HT Wi th HT HT HT P158/2/2/PO1 540 1 441 302 309 181 P158/2/2/PO2 540 2 385 332 408 298 P158/2/2/PO3 610 2 406 324 374 212 P158/2/2/PO4 650 4 360 292 220 140 We aremakingheattreatments and mechanical property tests TEST’S Result’s of Test - 7 -

  8. TEST’S Microhardness - 8 -

  9. P158/2/2/PO2C 300x P158/2/2/PO1C 150x 1mm 171 HV0,1 1mm 147 HV0,1 1mm 165 HV0,1 P158/2/2/PO3C 100x P158/2/2/PO2C 100x 179 HV0,1 178 HV0,1 670 HV0,1 188 HV0,1 173 HV0,1 403 HV0,1 165 HV0,1 182 HV0,1 193 HV0,1 183 HV0,1 179 HV0,1 153 HV0,1 185 HV0,1 172 HV0,1 308 HV0,1 164 HV0,1 183 HV0,1 449 HV0,1 191 HV0,1 188 HV0,1 935 HV0,1 418 HV0,1 403 HV0,1 240 HV0,1 475 HV0,1 707 HV0,1 988 HV0,1 191 HV0,1 393 HV0,1 324 HV0,1 327 HV0,1 423 HV0,1 251 HV0,1 172 HV0,1 191 HV0,1 989 HV0,1 423 HV0,1 468 HV0,1 429 HV0,1 167 HV0,1 417 HV0,1 412 HV0,1 439 HV0,1 363 HV0,1 354 HV0,1 418 HV0,1 393 HV0,1 181 HV0,1 423 HV0,1 272 HV0,1 408 HV0,1 439 HV0,1 439 HV0,1 389 HV0,1 450 HV0,1 283 HV0,1 450 HV0,1 1mm 331 HV0,1 1mm 331 HV0,1 1mm 398 HV0,1 TEST’S Microhardnessinmeltingsarea - 9 -

  10. Structuraltests 304L; intergranularcorrosion. TEST’S - 10 -

  11. TEST’S STRUCTURE OF BOND, DIFFUSSIONLAYER - 11 -

  12. SCHEDULE OF CARBON CONTENTS IN DIFFUSSION LAYER TEST’S SCHEDULE OF ELEMENTS IN DIFFUSSIONLAYER - 12 -

  13. ACCUMULATION OF CARBON IN DIFFUSSION LAYER TEST’S CHANGE OF SCHEDULE OF ELEMENTS IN DIFFUSIONLAYERAFTERHEATTRAETMENT - 13 -

  14. TEST’S Conclusions 1. HEAT TREATMENT MAKES DECREASING HARDENING IN BOTH MATERIALS AND IN BOND ZONE. 2. ACCUMULATION OF CARBON IN DIFFUSSION LAYER CAN MAKE INCREASING OF ITS FRAGILE WHAT MEANS ALSO DECREASING OF BOND STRENGHT Negative … 3. ECXALATION OF CHROMIUM CARBIDE ON THE BORDER OF GRAINS IN AUSTENITIC STAINLESS STEEL CAN MAKE DECREASING ITS RESISTANCE FOR INTERGRANULAR CORROSION Negative … BECAUSE OF OBSERVED DECREASNG OF STRENGTH OF BOND ZONE AND BECASUE OF UNPROFITABLE PHENOMENONS DESCRIBED IN POINT 2 AND 3 IN CONCLUSIONS, HEAT TRAETMENT OF CLADS TITANIUM – AUSTENITIC STAINLESS STEEL SEEMS TO BE INEXPEDIENT. Positive… - 14 -

  15. COMPANY CHARACTERISTIC SME Zakład Technologii Wysokoenergetycznych „EXPLOMET” Gałka, Szulc Sp.j. High-Energy Techniques Works xplomet • Employment: 6 workers • Seat: 860 m2 , including: • room and workshop, • social back-up facilities, • store rooms, • offices. Company details: Address: ul. Oświęcimska 100H, 45-641 Opole, POLAND Tel.: +48 (077) 45 17 817; 45 17 818; 45 17 819 45 62 374, Fax: +48 (077) 45 62 511 E-mail: explomet@op.onet.pl ; biuro@explomet.pl; http:// www.explomet.pl - 15 -

  16. Thankyou for attention…… W prezentacji wykorzystano materiały firmy EXPLOMET S.C. oraz Politechniki Opolskiej - 16 -

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