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ZnO /metal layered 3D Photonic crystals. Michael McMaster , Dr. Tom Oder, Dr. Donald Priour. Dept. of Physics and Astronomy, Youngstown State University, Youngstown, OH. What to Expect. What is a Photonic Crystal? Experimental Procedure Modeling/Results Conclusion. Photonic Crystal.

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ZnO /metal layered 3D Photonic crystals

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Zno metal layered 3d photonic crystals

ZnO/metal layered 3D Photonic crystals

Michael McMaster, Dr. Tom Oder, Dr. Donald Priour

Dept. of Physics and Astronomy,

Youngstown State University, Youngstown, OH


Zno metal layered 3d photonic crystals

What to Expect

  • What is a Photonic Crystal?

  • Experimental Procedure

  • Modeling/Results

  • Conclusion


Zno metal layered 3d photonic crystals

Photonic Crystal

  • “Photonic crystals are materials patterned with a periodicity in dielectric constant, which can create a range of ‘forbidden’ frequencies called a photonic bandgap. Photons with energies lying in the bandgap cannot propagate through the medium. This provides the opportunity to shape and mould the flow of light for photonic information technology.”

    • J.D. Joannopoulos, Pierre R. Villeneuve & Shanhui Fan

  • Applications include

  • Waveguides

  • LED light extraction

  • Ultrafast photonic crystal nanocavity laser

  • High speed communication

  • High speed information processing


Zno metal layered 3d photonic crystals

CallophrysGryneus

Vinodkumar et. Al. (2010)


Zno metal layered 3d photonic crystals

Peacock

Paridessesostris

Weevil and two Longhorns

Vinodkumar et. Al. (2010)

CERN Courier (2005)

Vigneron et. Al. (2012)


Zno metal layered 3d photonic crystals

Joannopoulos et. Al. (2008)


Zno metal layered 3d photonic crystals

Pillars Comprise a 3-D Photonic Crystal


Zno metal layered 3d photonic crystals

ZnO/Cr and ZnO/Al Multilayer Films

  • Substrate: double-side polished sapphire

  • Base Pressure: 10-7 mtorr

  • Preheat temperature:~700°C

  • Depositions temperature: 300°C

  • Deposition pressure: 10 mtorr

  • Ambient gas: Ar

  • Flow Rate: 10 sccm

  • Presputter: 3 min

  • ZnO Buffer Layer: 250 nm

  • Layer thicknesses:

    • ZnO/Cr (120 nm/12 nm)x10

    • ZnO/Cr (90 nm/ 5nm) x10

    • ZnO/Al (170 nm/ 5nm) x8


Zno metal layered 3d photonic crystals

How can we make 3-D Photonic Crystals?

Bottom Up

Top Down

FIB

Holes in 1-D crystals

Accurate, small feature size

  • Shadow mask sputtering

  • Periodic Array of Pillars

  • Quick and easy


Zno metal layered 3d photonic crystals

Some Quick Physics Facts

  • Index of Refraction:

  • Snell’s law

  • The Electric Field Equation:


Zno metal layered 3d photonic crystals

Mathematical Interlude

n1 n2 n3 … nN-1nN ns

A0 A1 A2 … … AN As

B0 B1 B2 … … BNBs

x0 x1 x2 … … xNxs

The Electric Field can be shown for different refractive indices as:

So we get a vector representing the amplitudes of the wave function.

Yeh. (2004)


Zno metal layered 3d photonic crystals

Mathematical Interlude (continued)

We can describe light at the interface of materials with different refractive indices with the dynamical matrices:

so that light passing through the interface responds such that

.

Also, as it travels through a material, the change is shown by the transfer matrix:

Yeh. (2004)


Zno metal layered 3d photonic crystals

Mathematical Interlude (Recap)

  • By acting on the vector representing light passing through the system with the matrices describing the environment we can predict the transmission spectrum.

  • Recall:

    But metals have an imaginary index of refraction (n) so

    let’s write:

    But Φhas real an imaginary parts Re(Φ) and Im(Φ) so

    where we see the Decay term.

Yeh. (2004)


Zno metal layered 3d photonic crystals

1-D Photonic Crystals

  • Refractive Indices in Visible Spectrum

    • ZnO2.0

    • Cr3.2

    • Al1.3

  • Layer thicknesses of samples:

    • ZnO/Cr (120 nm/12 nm)x10

    • ZnO/Cr (90 nm/ 5nm) x10

    • ZnO/Al (170 nm/ 5nm) x8


Zno metal layered 3d photonic crystals

Transmission Spectrum

Actual Transmission Spectrum

Theoretical Transmission Spectrum

?


Zno metal layered 3d photonic crystals

After Annealing

ZnO/Cr 1-D photonic Crystal

Theoretical Model


Zno metal layered 3d photonic crystals

After Annealing

ZnO/Cr 1-D photonic Crystal

Theoretical Model


Zno metal layered 3d photonic crystals

Remember those cosines?

ZnO/Cr (120nm/12nm)x10

Theoretical Model

Photonic Crystal

Not a Photonic Crystal


Zno metal layered 3d photonic crystals

We can Control the Band-Gap!

(this Time in Blue)

Band-Gap

ZnO/Cr 1-D photonic Crystal

Theoretical Model


Zno metal layered 3d photonic crystals

Aluminum

  • Band-gap is maximized when n1d1=n2d2

  • nZnO=2.0nAl=1.3

    • ZnO/Al (170 nm/ 5nm) x8

  • We predict a smaller band-gap

ZnO/Al 1-D photonic Crystal

Theoretical

Joannopoulos et. Al. (2008)


Zno metal layered 3d photonic crystals

EDX Results (Not Chromium Oxide)

ZnO/Cr (120 nm/12 nm)x10

Expected Transmission Spectrum if Chromium had oxidized.

(CrO3 refractive index 2.55)

ZnO/Cr (90 nm/ 5nm) x10

ZnO/Al (170 nm/ 5nm) x8


Zno metal layered 3d photonic crystals

Annealing in Different Gas


Zno metal layered 3d photonic crystals

4-Point Probe Results

Bulk Resistivity (Ω∙cm)

Pre AnnealingPost Annealing

ZnO/Cr (120 nm/12 nm)x10.01215

ZnO/Cr (90 nm/ 5nm) x10.0027310

ZnO/Al (170 nm/ 5nm) x8too resistive.095


Zno metal layered 3d photonic crystals

What Next???

  • Produce 3-D photonic crystals

  • using Shadow mask or FIB

  • Model in higher dimension

  • TEM/AFM for layer thickness

What we Expect

What we Hope For

  • Evidence of 3-D from diffraction pattern

  • Measureable band-gaps in oblique directions

  • Improved modeling

  • both polar and radial angle band-gap dependance

  • Predict band-gap

  • Test the effect of electric field on optical the band-gap


Zno metal layered 3d photonic crystals

References

  • VinodkumarSaranathan, Chinedum O. Osuji, Simon G. J. Mochrie, HeesoNoh, Suresh Narayanan, Alec Sandy, Eric R. Dufresne, and Richard O. Prum. Structure, function, and self-assembly of single network gyroid (I4132) photonic crystals in butterfly wing scales PNAS 107 (26) 11676-11681 (2010).

  • Joannopoulos, John D., Steven G. Johnson, Joshua N. Winn, Robert D. Meade. Photonic Crystals Modeling the Flow of Light Second Edition. Princeton University Press (2008).

  • Yeh,Pochi. Optical Waves In Layered Media: 2nd (second) Edition. Whiley Press (2004).

  • Peacock feathers prove photonic crystals cast brown light in nature. CERN Courier. Aug 22, 2005

    • JoannopoulosJ.D. , Pierre R. Villeneuve and ShanhuiFan. Photonic Crystals: putting a new twist on light. Nature 386 (13) 143-149 (1997)

    • Vigneron, Jean Pol, and Priscilla Simonis. Natural photonic crystals.Physica B Condensed Matter 407 (20) 4032-4036 (2012)


Zno metal layered 3d photonic crystals

Acknowledgements

  • We gratefully acknowledge support of funds from NSF (DMR#1006083) and from the State of Ohio (Third Frontier - RC-SAM).

  • Support and funds from Youngstown State University

  • I would also like to thank Dr. Jim Andrews, Jessica Shipman and Matt Kelly and Dr. George Yates for helping with this project.


Zno metal layered 3d photonic crystals

Any Questions?

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