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c.HNO 3 c. H 2 SO 4. c. H 2 SO 4. Sn + c.HCl. reflux. <55 C. reflux. Friedel-Crafts alkylation. Friedel-Crafts acylation. RCl AlCl 3 reflux. RCOCl Or (RCO) 2 O AlCl 3. substitution. substitution. Cl 2 (g) AlCl 3 room temp. Br 2 (l) FeBr 3 (or Fe) room temp. substitution.

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c. H 2 SO 4

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c.HNO3

c. H2SO4

c. H2SO4

Sn + c.HCl

reflux

<55C

reflux

Friedel-Crafts

alkylation

Friedel-Crafts

acylation

RCl

AlCl3

reflux

RCOCl

Or (RCO)2O

AlCl3

substitution

substitution

Cl2(g)

AlCl3

room temp

Br2(l)

FeBr3 (or Fe)

room temp

substitution

substitution

reduction

substitution

substitution

Notes:1.The Friedel-Crafts reactions are carbon-carbon bond forming reactions.

2.All substitution reactions of arenes are electrophilic.


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