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Journal of Coordination Chemistry Vol. 64, No. 17, 10 September 2011, 3012–3021 Synthesis and characterization of lead(II) complexes with substituted 2,29-bipyridines, trifluoroacetate, and furoyltrifluoroacetonate

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Downloaded by york university libraries at 07 04 21 september 2011

Journal of Coordination Chemistry

Vol. 64, No. 17, 10 September 2011, 3012–3021

Synthesis and characterization of lead(II) complexes with substituted 2,29-bipyridines, trifluoroacetate, and furoyltrifluoroacetonate

FARZIN MARANDI*y, ZAHRA NIKPEYy, MARYAM KHOSRAVIy, SAEIDEH HOSSEINIz, HOONG-KUN FUNx and MADHUKAR HEMAMALINIx

yChemistry Department, Payame Noor University, 19395-4697 Tehran, I. R. of Iran

zChemistry Department, Islamic Azad University, Karaj Branch, Karaj, I. R. of Iran

xX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia,

11800 USM, Penang, Malaysia

(Received 11 April 2011; in final form 8 July 2011)

Two substituted 2,20 -bipyridine lead(II) complexes, [Pb(5,50 -dm-2,20 -bpy)(tfac)2]n (1) (5,50 -dm-2,20 -bpy ¼ 5,50 -dimethyl-2,20 -bipyridine and tfac ¼ trifluoroacetate) and [Pb2(4,40 - dmo-2,20 -bpy)2(ftfa)4] (2) (4,40 -dmo-2,20 -bpy ¼ 4,40 -dimethoxy-2,20 -bipyridine and ftfa ¼fur- oyltrifluoroacetonate), have been synthesized and characterized by elemental analysis, IR, 1H NMR, and 13C NMR spectroscopies, thermal behavior, and X-ray crystallography. Complexes

1 and 2 are 1D coordination polymer and dinuclear complex, respectively. The supramolecular features in these complexes are guided by weak directional intermolecular interactions.

Keywords: Lead(II); Substituted 2,20 -bipyridine; Intermolecular interactions

1. Introduction

Research on supramolecular chemistry has developed rapidly to produce new materials with interesting structural features and potential applications, one of the most active branches in current coordination chemistry [1, 2]. By self-assembly of well-designed organic ligands and metal ions under appropriate conditions, a variety of metallosu- pramolecular architectures have been achieved. Hydrogen bonds also have been used to organize coordination compounds; however, – interactions have been scarcely studied in the design of crystals of coordination compounds [1, 2]. Shimoni and Glusker [3], however, have pointed out that although C–H F–C interactions are weak compared to C–H O–C interactions, their contributions cannot be ignored in determining molecular packing in complexes and crystals. A number of studies have been carried out to explore the different modes of interactions involving the C–F group [4]. Row et al. [5] have been involved in investigation of interactions of organic fluorine in different chemical environments and have demonstrated that fluorine provides

*Corresponding author. Email: [email protected]

Journal of Coordination Chemistry

ISSN 0095-8972 print/ISSN 1029-0389 online 2011 Taylor & Francis

DOI: 10.1080/00958972.2011.609593

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