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Chapter Twenty

Chapter Twenty. The Representative Elements- Groups 5A Throught 8. Representative Elements: Groups 5A-8A. Figure 20.1 The Molecules of the Types MX 3 , MX 5 , and MX 6 Formed by Group 5A Elements. Figure 20.2 The Structures of the Tetrahedral MX 4 + and Octahedral MX 6 - Ions.

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Chapter Twenty

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  1. Chapter Twenty The Representative Elements- Groups 5A Throught 8

  2. Representative Elements: Groups 5A-8A

  3. Figure 20.1 The Molecules of the Types MX3, MX5, and MX6 Formed by Group 5A Elements

  4. Figure 20.2 The Structures of the Tetrahedral MX4+ and Octahedral MX6- Ions

  5. Figure 20.5 The Haber Process for the Manufacture of Ammonia

  6. Figure 20.6 The Nitrogen Cycle

  7. Figure 20.7 The Molecular Structure of Hydrazine (N2H4)

  8. Figure 20.8 The Molecular Orbital Energy-Level Diagram for Nitric Oxide (NO)

  9. Figure 20.9 The Ostwald Process

  10. Figure 20.10a The Molecular Structure of HNO3

  11. Figure 20.11 (a) The P4 Molecule Found in White Phosphorus (b) The Crystalline Network Structure of Black Phosphorous (c) The Chain Structure of Red Phosphorus

  12. Figure 20.12 The Structures of P4O6 and P4O10

  13. Figure 20.13 a & b (a) The Structure of Phosphorous Acid (H3PO3). (b) The Structure of Hypophosphorous Acid (H3PO2)

  14. Figure 20.14 a & b Structures of the Phosphorus Halides

  15. Figure 20.15 The Frasch Process for Recovering Sulfur from Underground Deposits

  16. Figure 20.16 a & b (a) The S8 Molecule (b) Chains of Sulfur Atoms in Viscous Liquid Sulfur

  17. Figure 20.18 Structure of Sulfur Dioxide

  18. Figure 20.19 Resonance Structures of SO3

  19. Figure 20.20 Different Structures for Solid SO3 (a) S3O9 Rings (b) (SO3)x Chains

  20. Figure 20.22 The Structures of (a) SF4, (b) SF6, (c) S2F10 and (d) S2Cl2

  21. Figure 20.23 The Hydrogen Bonding Among HF Molecules in Liquid Hydrogen Fluoride

  22. Figure 20.24 The Structures of the Oxychloro Anions

  23. Figure 20.25 The Idealized Structures of the Interhalogens CIF3 and IF5

  24. Figure 20.26 The Structures of Several Known Xenon Compounds

  25. Samples Stored in a Liquid Nitrogen Tank

  26. An Inert-Atmosphere Box Used When Working with Oxygen-or Water-Sensitive Materials

  27. Nodules on the Roots of Pea Plants Contain Nitrogen-Fixing Bacteria

  28. Blowing Agents Such as Hydrazine are used to Produce Porous Plastics

  29. A Copper Penny Reacts with Nitric Acid

  30. The Phosphorus in Safety Matches Helps ignite the Flame in the Match

  31. Pouring Liquid Sulfur into Water to Produce Plastic Sulfur

  32. Figure 20.17 a & b (a) Crystals of Rhombic Sulfur (b) Crystals of Monoclinic Sulfur

  33. A Sulfur Deposit

  34. Melted Sulfur Obtained from Underground Deposits by the Frasch Process

  35. Figure 20.21 (a) A Beaker of Sucrose (table sugar) (b) Concentrated Sulfuric Acid Reacts with the Sucrose to Produce a Column of Carbon (c) Accompanied by an Intense Burnt-Sugar Odor

  36. Chlorine, Bromine, and Iodine

  37. A Candle Burning in an Atmosphere of Cl2(g)

  38. This Steuben Glass Design was Etched Using Hydrofluoric Acid

  39. Glasses with Photosensitve Lenses

  40. Neon, a Noble Gas, is Used in Luminescent Lighting

  41. Table 20.1 Selected Physical Properties, Sources, and Methods of Preparation for the Group 5A Elements

  42. Table 20.2 Some Common Nitrogen Compounds

  43. Table 20.3 Comparison of the Bond Lengths and Bond Energies for Nitric Oxide and the Nitrosyl Ion

  44. Table 20.4 Selected Physical Properties, Sources, and Methods of Preparation for the Group 6A Elements

  45. Table 20.5 Common Compounds of Sulfur with Various Oxidation States

  46. Table 20.6 Trends in Selected Physical Properties of the Group 7A Elements

  47. Table 20.7 Some Physical Properties, Sources, and Methods of Preparation for the Group 7A Elements

  48. Table 20.8 Some Physical Properties of the Hydrogen Halides

  49. Table 20.9 The Enthalpies and Entropies of Hydration for the Halide Ions

  50. Table 20.10 The Known Oxyacids of the Halogens

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