chemistry of aromatic compounds
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Chemistry of Aromatic Compounds

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Chemistry of Aromatic Compounds. Electrophilic Aromatic Substitution Directing Effects Side-chain Reactions Synthesis Nucleophilic Aromatic Substitution. Electrophilic Aromatic Substitution. EAS Reactions of Benzene. Bromination / Chlorination. Bromination Mechanism. Reaction Profile.

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chemistry of aromatic compounds

Chemistry of Aromatic Compounds

Electrophilic Aromatic Substitution

Directing Effects

Side-chain Reactions

Synthesis

Nucleophilic Aromatic Substitution

side chain reactions
Side Chain Reactions

1) Reduction of Aromatic Ketones

s n a criteria
“SNA” criteria:
  • Strongly deactivated ring
  • Leaving group
  • Deactivating group(s) ortho &/or para to leaving group (preferably)
  • Strong base (nucleophile) such as RO-, NH2-
with no ewg reaction conditions are more extreme elimination addition mechanism
With no EWG, reaction conditions are more extremeElimination/Addition Mechanism
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